Abstract A series of three lithium silylamides Li 2 Me 2 Si(NC 6 H 4 ‐2‐SR) 2 (R=Me, Ph, t Bu) were prepared from the reaction of the corresponding silylamines Me 2 Si(NH‐C 6 H 4 ‐2‐SR) 2 with n ‐butyl lithium. X‐ray single crystal structure analyses revealed the formation of dimers [Li 4 {Me 2 Si(NC…
Abstract The thioether‐functionalized aminosilanes Me 2 Si(NH‐C 6 H 4 ‐2‐SR) 2 (R=Ph, Me) were lithiated with n ‐BuLi and subsequently allowed to react with CuCl in the presence of PMe 3 . In the case of Me 2 Si(NH‐C 6 H 4 ‐2‐SPh) 2 , the dinuclear complex [Cu 2 {Me 2 Si(NC 6 H 4 ‐2‐SPh) 2 }(PMe 3 )…