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Dissertation
2010-06-22

Reactivity of (THF)4Ca(PPh2)2 in stoichiometric and catalytic reactions

Catalytic intermolecular hydrophosphanylation of alkynes and conjugated diynes with HPPh2 was achieved with the calcium based catalyst (thf)4Ca(PPh2)2 with very good yields and under mild conditions. Beside the enormous reactivity of (thf)4Ca(PPh2)2 regarding hydrophosphanylation reactions, the diphenylphosphanide...