In this work, the synthesis and structural characterization of the smallest possible member of the family of bis -functionalized {MnMo 6 O 24 } Anderson–Evans polyoxometalates (POMs) is reported. The synthesis of the title compound TBA 3 {[HC(CH 2 O) 3 ] 2 MnMo 6 O 18 } ( 1 ) was accomplished by using…
Excited‐state proton transfer (ESPT) roots in significantly increased acidities or basicities of up to ca. 10 p K a units in the excited state compared to the ground state. While organic photobases are either of “single use” in the case of photobase generators or are limited functionally by their UV…
This work presents the synthesis and structural characterization of a novel type of biscyclometalated Ir(III) complex, which is equipped with two iodoethynyl moieties on its 2,2′-bipyridine (bpy) ligand. Iodoethynyl moieties represent prominent donor systems for the formation of supramolecular structures…