Abstract By applying automated high‐throughput experimentation, 63 precipitation polymerizations of divinylbenzene and methacrylic acid were performed with a total of 1638 samples analyzed by gas chromatography (GC), nuclear magnetic resonance (NMR) spectroscopy, and scanning electron microscopy (SEM).…
Redox-active conjugated oligo(quinoxaline)s as potential visible light-transparent charge transport building blocks were synthesized, purified, and characterized. The Suzuki–Miyaura catalyst-transfer polymerization (SCTP) in the presence of an excess of monofunctional aryl halide led to quantitative…
Washington, DC: American Chemical Society, 2024-04-24
The COVID‐19 mRNA vaccines represent a milestone in developing non‐viral gene carriers, and their success highlights the crucial need for continued research in this field to address further challenges. Polymer‐based delivery systems are particularly promising due to their versatile chemical structure…
Online NMR measurements are introduced in the current study as a new analytical setup for investigation of the oxymethylene dimethyl ether (OME) synthesis. For the validation of the setup, the newly established method is compared with state‐of‐the‐art gas chromatographic analysis. Afterwards, the influence…
The supramolecular halogen bonding (XB) is utilized for the first time for the preparation of shape‐memory polymers. For this purpose, an iodotriazole‐based bidentate XB donor featuring a methacrylamide is synthesized. Free radical polymerization of the XB donor monomer together with butyl methacrylate,…
The ongoing digitalization is rapidly changing and will further revolutionize all parts of life. This statement is currently omnipresent in the media as well as in the scientific community; however, the exact consequences of the proceeding digitalization for the field of materials science in general…