We report the governing principles that regulate the activity of light-driven CO 2 reduction by a molecular photosensitizer bis(2,2′-bipyridine)-(4,4′-dinonyl-2,2′-bipyridine)-ruthenium(II) ( RuC 9 ) and a molecular catalyst (5,10,15,20-tetra(4-methylphenyl)porphinato)cobalt(II) ( CoTTP ) in supramolecular…
Washington, DC: American Chemical Society, 2026-02-25
In natural photosynthesis, light‐driven electron transfer across the thylakoid membrane enables efficient charge separation and the confinement of reaction spaces for generating NADPH and CO 2 and oxidation of water. These reactions are complementary redox reactions and require different reaction conditions…