3 Dokumente gefunden

Photocatalytic Reduction of Nicotinamide Co‐factor by Perylene Sensitized Rh III Complexes **

The ambitious goal of artificial photosynthesis is to develop active systems that mimic nature and use light to split water into hydrogen and oxygen. Intramolecular design concepts are particularly promising. Herein, we firstly present an intramolecular photocatalyst integrating a perylene‐based light‐harvesting…
Weinheim: Wiley-VCH, 2022-11-02

Pyrimidoquinazolinophenanthroline Opens Next Chapter in Design of Bridging Ligands for Artificial Photosynthesis **

The synthesis and detailed characterization of a new Ru polypyridine complex containing a heteroditopic bridging ligand with previously unexplored metal‐metal distances is presented. Due to the twisted geometry of the novel ligand, the resultant division of the ligand in two distinct subunits leads to…
Weinheim: Wiley-VCH, 2022-09-12

Intracellular photophysics of an osmium complex bearing an oligothiophene extended ligand

This contribution describes the excited‐state properties of an Osmium‐complex when taken up into human cells. The complex 1 [Os(bpy) 2 (IP‐4T)](PF 6 ) 2 with bpy=2,2′‐bipyridine and IP‐4T=2‐{5′‐[3′,4′‐diethyl‐(2,2′‐bithien‐5‐yl)]‐3,4‐diethyl‐2,2′‐bithiophene}imidazo[4,5‐ f ][1,10]phenanthroline) can…
Weinheim: Wiley-VCH, 2020-11-26