@Article{dbt_mods_00062461, author = {Alam, Shahidul and Anand, Aman and Islam, Md Moidul and Meitzner, Rico and Djoumessi, Aurelien Sokeng and Slowik, Josef and Teklu, Zekarias and Fischer, Peter and K{\"a}stner, Christian and Khan, Jafar I. and Schubert, Ulrich Sigmar and Laquai, Fr{\'e}d{\'e}ric and Hoppe, Harald}, title = {P3HT:PCBM polymer solar cells from a didactic perspective}, journal = {Journal of photonics for energy: JPE ; an SPIE e-journal}, year = {2022}, month = {Aug}, day = {23}, publisher = {SPIE-Intl Soc Optical Eng}, address = {Bellingham Wash.}, volume = {12}, number = {3}, keywords = {bulk-heterojunction polymer solar cells; poly(3-hexylthiophene); [6,6]-phenyl-C61- butyric acid methyl ester solar cells; thermal annealing; pre-and post-annealing}, abstract = {Here, we studied the influence of pre- and post-thermal annealing on the performance of polymer:fullerene bulk heterojunction solar cells using the conventional architecture, comprising a conjugated polymer, namely, poly(3-hexylthiophene-2,5-diyl) (P3HT) and a fullerene derivative [6,6]-phenyl-C60-butyric acid methyl ester (PC60BM) as a photoactive layer. The non-annealed active layer device exhibited a power conversion efficiency of <1 {\%} , which was significantly lower than the pre- and post-annealed devices. To investigate the impact of pre- and post thermal annealing on the natural morphological state of the polymer, regiorandom (P3HT-I) and regioregular (P3HT-II) type P3HT were compared in photoactive layers. In general, P3HT-I is amorphous, whereas P3HT-II is semi-crystalline. Changes in solar cell performance were associated with changes in carrier extraction efficiencies influenced by the annealing conditions. The charge photogeneration processes were investigated using spectroscopic techniques, including electroluminescence, steady-state, and time-resolved photoluminescence spectroscopy. Finally, to explore the morphological changes upon annealing, atomic force microscopy and electroluminescence imaging measurements were performed on films and solar cells, respectively.}, issn = {1947-7988}, doi = {10.1117/1.JPE.12.035501}, url = {https://www.db-thueringen.de/receive/dbt_mods_00062461}, url = {http://uri.gbv.de/document/gvk:ppn:1820826414}, url = {http://uri.gbv.de/document/gvk:ppn:64297490X}, url = {https://doi.org/10.1117/1.JPE.12.035501}, file = {:https://www.db-thueringen.de/servlets/MCRFileNodeServlet/dbt_derivate_00064776/1947-7988_12_2022_3_035501.pdf:PDF}, language = {en} }