γ‐Valerolactone as Sustainable and Low‐Toxic Solvent for Electrical Double Layer Capacitors

GND
129961678X
Affiliation
Institute for Technical Chemistry and Environmental Chemistry Friedrich-Schiller-University Philosophenweg 7a 07743 Jena Germany
Teoh, Khai Shin;
Affiliation
Dipartimento di Scienze Chimiche Università degli Studi di Napoli Federico II, Complesso Universitario di Monte S. Angelo via Cintia 21 80216 Napoli Italy
Melchiorre, Massimo;
GND
1299618952
Affiliation
Institute for Technical Chemistry and Environmental Chemistry Friedrich-Schiller-University Philosophenweg 7a 07743 Jena Germany
Kreth, Fabian Alexander;
GND
1283861836
Affiliation
Institute for Technical Chemistry and Environmental Chemistry Friedrich-Schiller-University Philosophenweg 7a 07743 Jena Germany
Bothe, Annika;
GND
1299620620
Affiliation
Institute for Technical Chemistry and Environmental Chemistry Friedrich-Schiller-University Philosophenweg 7a 07743 Jena Germany
Köps, Lukas;
Affiliation
Dipartimento di Scienze Chimiche Università degli Studi di Napoli Federico II, Complesso Universitario di Monte S. Angelo via Cintia 21 80216 Napoli Italy
Ruffo, Francesco;
ORCID
0000-0002-2887-8312
Affiliation
Institute for Technical Chemistry and Environmental Chemistry Friedrich-Schiller-University Philosophenweg 7a 07743 Jena Germany
Balducci, Andrea

Abstract In this work, γ‐valerolactone (GVL), a green solvent based on largely available biomass (carbohydrates), highly biodegradable, and with low eco‐toxicological profile, was used as electrolyte component in energy storage devices. This solvent allowed the realization of electrolytes with good transport properties and high thermal stability, which could be successfully applied in electrical double layer capacitors (EDLCs). GVL‐based EDLCs could operate at 2.7–2.9 V and displayed good performance in term of capacitance, cycling stability, as well as specific energy and power. The results of this study indicate that the use of solvent obtained from largely available natural sources is a feasible strategy for the realization of sustainable and safe electrolytes for EDLCs.

Sustainable solvent : The concept of using solvent γ‐valerolactone (GVL) derived from sustainable feedstocks as electrolyte component in electrical double layer capacitors (EDLCs) is implementable. GVL‐based electrolytes, with an operating voltage of 2.7–2.9 V, present high capacitance retention and good specific energy as well as power in EDLCs. image

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