Electromagnetic levitation (EML) was employed for studying the velocity and morphology of the solidification front as a function of undercooling of metallic materials. The limitation of the EML technique with respect to low melting alloys that emit outside the visible light spectrum was overcome by employing state-of-the-art high-speed mid-wavelength infrared cameras (MWIR cameras) with a photon detector. Due to the additional thermography contrast provided by the emission contrast of the solid and liquid phases, conductor, and semi-conductor, the pattern formation of Al-based alloys was studied in detail, revealing information on the nucleation, phase selection during solidification, and the influence of convection.