Mathematical modeling of bulk and directional crystallization with the moving phase transition layer

GND
1279003006
ORCID
0000-0003-4587-2630
Affiliation
Otto‐Schott‐Institut für Materialforschung Friedrich Schiller Universität Jena Jena Germany
Toropova, Liubov V.;
ORCID
0000-0001-5894-8126
Affiliation
Laboratory of Multi‐Scale Mathematical Modeling, Institute of Natural Sciences and Mathematics Ural Federal University Ekaterinburg Russian Federation
Aseev, Danil L.;
Affiliation
Laboratory of Multi‐Scale Mathematical Modeling, Institute of Natural Sciences and Mathematics Ural Federal University Ekaterinburg Russian Federation
Osipov, Sergei I.;
ORCID
0000-0002-2490-160X
Affiliation
Laboratory of Multi‐Scale Mathematical Modeling, Institute of Natural Sciences and Mathematics Ural Federal University Ekaterinburg Russian Federation
Ivanov, Alexander A.

This paper is devoted to the mathematical modeling of a combined effect of directional and bulk crystallization in a phase transition layer with allowance for nucleation and evolution of newly born particles. We consider two models with and without fluctuations in crystal growth velocities, which are analytically solved using the saddle‐point technique. The particle‐size distribution function, solid‐phase fraction in a supercooled two‐phase layer, its thickness and permeability, solidification velocity, and desupercooling kinetics are defined. This solution enables us to characterize the mushy layer composition. We show that the region adjacent to the liquid phase is almost free of crystals and has a constant temperature gradient. Crystals undergo intense growth leading to fast mushy layer desupercooling in the middle of a two‐phase region. The mushy region adjacent to the solid material is filled with the growing solid‐phase structures and is almost desupercooled.

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